UASB-SBR工艺处理城市生活污水的研究

研究了UASB工艺处理城市生活污水的可行性，通过UASB与SBR组合工艺的运行实验，得出在水力停留时间3h时，COD去除率为61．67％-82．32％，出水COD达到国家污水排放二级标准。在氮磷去除效果不佳的情况下，采用SBR工艺处理后，其出水COD、SS、氮、磷等指标均达到国家污水一级排放标准。     

3000m~3/h排烟循环流化床脱硫工艺中试实验研究

介绍了采用真实烟气的 30 0 0m3 /h排烟循环流化床烟气脱硫工艺 (CFB FGD)及其中间试验装置 ,通过实验研究了钙硫摩尔比 (Ca/S)、近绝热饱和温度差 (ΔT)、烟气湿度、喷水量、入口SO2 浓度、浆液雾化质量、脱硫灰循环等对脱硫效果的影响。实验表明 ,CFB FGD工艺在停留时间小于 6s、烟气流速v =4— 6m/s、Ca/S =1.2、ΔT =10— 12℃时可实现高达 90 %的脱硫效率。     

Characterization of the reactivity of limestones with SO2 in a fluidized bed reactor

The reaction between SO₂ and calcined limestone particles has been studied in a fluidized bed combustor. Measurements of sorbent reactivity with SO₂ were made for small batches of limestone injected into the combustor. Simultaneous continuous combustion of bituminous coal provided conditions like those of a boiler for study of the sulphation reaction. A semi-empirical rate model of the CaO-SO₂ reaction has been developed. External mass transfer of SO₂, diffusion within the particles and chemical reaction are taken into account. The limestone reactivity with SO₂ is characterized by two parameters which are dependent on the temperature and sorbent particle size. A model for predicting the limestone requirements in a fluidized bed boiler has been developed. Parameters from the batch experiments are included. The predictions for sulfur retention agree with the experimental results. In addition, effects of operating conditions (gas velocity, recycle, limestone particle size) on the retention of SO₂ were simulated using the model.     

Observation of 3‐D Structure of Bubbles in a Fluidized Catalyst Bed

The interface area between the bubble and emulsion phases in a fluidized catalyst bed is one of the important parameters used to analyze and design the fluidized bed reactor. We used a fast‐scanning X‐ray CT system to observe the bubble shape and structure. We then obtained the transient 2‐dimensional cross sectional gas‐phase distribution in a fluidized catalyst bed. Using image‐processing techniques, pseudo 3‐dimensional images of the bubbles were reconstructed. The bubble structure was studied based on the 3‐dimensional images and the previously obtained results in a 2‐dimensional fluidized bed. It was found that the bubble shape was not spherical but complicated, and that the bubbles ascending in a fluidized catalyst bed consisted of some smaller bubbles.     

模拟三相流化床中颗粒尺寸对单气泡传质系数的影响

本文在模拟三相流化床中,测量了单气泡的传质系数,实验结果表明颗粒直径对气-液传质系数影响显著。颗粒直径较大时,传质系数有明显提高。     

IMAGING OF PARTICLE MOTION IN FLUID-SOLID SYSTEMS USING A GAMMA CAMERA

A new approach is presented for the characterization of particle motion in fluid-solid systems based on dynamic imaging with a gamma scintillation camera. A two-dimensional spouted bed of 200-500 micron diameter anion exchange resin beads was used as a test system. One or several beads were radiolabeled with the 140 keV gamma emitting radionuclide 99m-Tc pertechnetate, and particle velocity, panicle path, the spatial distribution of particle residence times, and local bed density were determined from the measured temporal and spatial distributions of particle activity. While care must be exercised in the interpretation of data when the scale for changes in the spatial distribution of activity approaches the limits of camera resolution, the method is quantitative, non-invasive, and well suited to the study of systems having symmetry in one spatial dimension.     

WALL AND PARTICLE-SHAPE EFFECTS ON HEAT TRANSFER IN PACKED BEDS

The effective radial thermal conductivity and apparent heat transfer coefficient for a packed bed were experimentally determined for beds of spheres, full cylinders and hollow cylinders, for flow rates giving particle Reynolds numbers in the range 100-1000, and for tube to particle diameter ratios of 5-12. Over these ranges the radial Peclet number Pe_r showed significant dependence on solid conductivity, gas flow rate and particle shape, while the wall Biot number Bi showed significant dependence on tube to particle diameter ratio, gas flow rate and particle shape. These dependencies were predicted well by equations incorporating the effects of these variables into individual gas and solid phase parameters, which were then combined to give the effective or lumped parameters     

Zernike矩结合Sigmoid曲线拟合边缘检测方法

为了改进Zernike矩边缘检测方法对非直线边缘检测精度低的弱点,提出了一种改进的基于Zernike矩方法和Sigmoid拟合法的边缘检测方法。用Zernike矩边缘检测方法检测边缘,然后用Sigmoid拟合方法检测边缘,根据边缘类型对两种方法检测的边缘结果进行加权求和,所得结果为边缘位置。分别利用理想图像和实际工业CT图像进行了实验验证,实验结果表明对非直线边缘的检测,该方法检测精度相对于Zernike矩方法提高了一个数量级。     

Voidage characteristics and prediction of bed expansion in liquid-solid inverse fluidized bed

Studies on voidage fluctuations, axial voidage profile and bed expansion are carried out by measuring the local void fraction using particles of wide ranging characteristics in liquid-solid inverse fluidized bed. The quality of fluidization is elucidated by the local voidage fluctuations. The RMS voidage fluctuation depicts a maximum with respect to average bed void fraction and increases with increase in Archimedes number. The fluidization quality has been quantified using average normalized RMS voidage fluctuation in terms of Transition number. The axial void fraction is almost uniform throughout the bed except for particles with size distribution. All the literature and present experimental data on bed expansion are unified in terms of Richardson and Zaki equation using experimental terminal velocities. A new correlation is proposed for predicting the wall effect corrected experimental terminal velocities, as a substitute for standard drag equation. The bed expansion data are also predicted using the drift flux model.     

1993年中国化学工业

１９９３年化工系统完成总产值１７９６．３亿元，比上年增长７．３％。全年完成固定资产投资２３０多亿元，比上年增长１９％。全年进出口总额达１８７亿美元，比上年增长１６．１％。但化学工业发展速度低于全国工业的增长速度。